Inhomogeneous swelling of a gel in equilibrium with a solvent and mechanical load

نویسندگان

  • Wei Hong
  • Zishun Liu
  • Zhigang Suo
چکیده

A network of polymers can imbibe a large quantity of a solvent and swell, resulting in a gel. The swelling process can be markedly influenced by a mechanical load and geometric constraint. When the network, solvent, and mechanical load equilibrate, the gel usually swells by a field of inhomogeneous and anisotropic deformation. We show that this field in the swollen gel is equivalent to that in a hyperelastic solid. We implement this theory in the finite-element package, ABAQUS, and analyze examples of swelling-induced deformation, contact, and bifurcation. Because commercial software like ABAQUS is widely available, this work may provide a powerful tool to study complex phenomena in gels.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Modeling and simulation of buckling of polymeric membrane thin film gel

The swellingand deswelling-induced instabilities of various membrane structures are simulated using the inhomogeneous field theory of a polymeric network in equilibrium with a solvent and mechanical load/constraint and the Finite Element subroutine developed in ABAQUS. The simulating results of these membrane gels are compared with available experimental results, and a reliable prediction in de...

متن کامل

Pattern formation in plants via instability theory of hydrogels

In this paper, we demonstrate how deformation patterns of leaves and fruits in growing and drying processes can be described via the inhomogeneous field theory. The distorted deformation of ribbed leaves and the ridge formation on fruit surfaces can be understood as the energy-minimizing mechanical buckling patterns. The swelling and de-swelling induced instabilities of various membrane structu...

متن کامل

A Variational Approach and Finite Element Implementation for Swelling of Polymeric Hydrogels Under Geometric Constraints

A hydrogel consists of a cross-linked polymer network and solvent molecules. Depending on its chemical and mechanical environment, the polymer network may undergo enormous volume change. The present work develops a general formulation based on a variational approach, which leads to a set of governing equations coupling mechanical and chemical equilibrium conditions along with proper boundary co...

متن کامل

A coupled theory of fluid permeation and large deformations for elastomeric materials

An elastomeric gel is a cross-linked polymer network swollen with a solvent (fluid). A continuum-mechanical theory to describe the various coupled aspects of fluid permeation and large deformations (e.g., swelling and squeezing) of elastomeric gels is formulated. The basic mechanical force balance laws and the balance law for the fluid content are reviewed, and the constitutive theory that we d...

متن کامل

Electroresponsive Acrylic Gels

This articles is comprised of two parts: a) an experimental investigation on the behavior of an acrylic gel under DC electric field and b) a physico - mathematical description.a) Gel rods made of poly [acrylamide-co-bisacrylamide] were partially hydrolyzed to different extents at pH 12 by teteramethylethylene diamine. Equlibrium properties of the resulting gels rods (water content,...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2008